N-donor complexes of palladium as catalysts for Suzuki cross-coupling reactions in ionic liquids

被引：75

作者：

Mathews, CJ

Smith, PJ

Welton, T ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] Syngenta, Jealotts Int Res Ctr, Bracknell RG42 6ET, Berks, England

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 214卷 / 01期

关键词：

cross-coupling reaction; ionic liquids; palladium imidazole complexes;

D O I：

10.1016/j.molcata.2003.11.030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Palladium imidazole complexes have been used as catalyst precursors for the Suzuki cross-coupling reaction in 1-butyl-3-methylimidazolium-based ambient temperature ionic liquids. The system provides a stable, recyclable method for iodo- and bromoarenes. The preferred reaction conditions are explored and the effect of changing the ionic liquid components is investigated. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：27 / 32

页数：6

共 66 条

[1] Synthesis of new chiral diimine palladium(II) and nickel(II) complexes bearing oxazoline- and myrtanyl-based nitrogen ligands.: Crystal structure of the C2-symmetric complex [{(1R,2S)-inda-box}PdCl2] [J].