On-line electrochemistry - MS and related techniques

被引：83

作者：

Diehl, G

Karst, U

机构：

[1] Univ Twente, Dept Chem Anal, NL-7500 AE Enschede, Netherlands

[2] Univ Twente, MESA Res Inst, NL-7500 AE Enschede, Netherlands

来源：

ANALYTICAL AND BIOANALYTICAL CHEMISTRY | 2002年 / 373卷 / 06期

关键词：

electrochemistry; mass spectrometry; hyphenated techniques; liquid chromatography; electrospray;

D O I：

10.1007/s00216-002-1281-3

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

This review summarizes publications on the on-line coupling of electrochemistry with mass spectrometry. After a brief historic introduction it is divided into three parts, organized in order of increasing complexity of the experimental arrangement. The first section deals with the use of the electrospray ion source as an electrochemical reactor for oxidation or reduction reactions. It is followed by the second part which covers the hyphenation of different kinds of electrochemical flow cell with a variety of ionization interfaces. The last section focuses on the online coupling of chromatographic techniques with electrochemical flow cells and mass spectrometry.

引用

页码：390 / 398

页数：9

共 110 条

[1] Analysis of electrolysis reactions of metal complexes using on-line electrospray ionization mass spectrometry with a compact electrolytic flow-through cell [J].