cis-Diaquabis(2,2'-bipyrimidine-N,N')cobalt(II) diperchlorate dihydrate, [Co(C8H6N4)(2)(H2O)(2)](ClO4)(2).2H(2)O

被引：5

作者：

Brunzelle, J ^{[1
]}

Fitch, A ^{[1
]}

Wang, YL ^{[1
]}

Pavkovic, SF ^{[1
]}

机构：

[1] LOYOLA UNIV,DEPT CHEM,CHICAGO,IL 60626

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196010426

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex cation in the title structure has a distorted octahedral coordination geometry with cobalt bonded to two bidentate bipyrimidine (bpm) ligands and two water molecules in cis positions. The structure has crystallographically imposed twofold symmetry.

引用

收藏

页码：2984 / 2987

页数：4

相关论文

共 10 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].

ALLEN, FH ;

KENNARD, O ;

WATSON, DG ;

BRAMMER, L ;

ORPEN, AG ;

TAYLOR, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19

[2] 2,2'-BIPYRIMIDINE (BIPYM)-BRIDGED DINUCLEAR COMPLEXES .4. SYNTHESIS, CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF [CO2(H2O)8(BIPYM)][NO3]4, [CO2(H2O)8(BIPYM)][SO4]2.2H2O AND [CO2(BIPYM)3(NCS)4] [J].

DEMUNNO, G ;

JULVE, M ;

LLORET, F ;

FAUS, J ;

CANESCHI, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (08) :1175-1183

[3] STRUCTURE OF BIS(2,2'-BIPYRIMIDINE-N,N')DICHLOROCOBALT(II), [CO(BPM)2CL2] [J].

DEMUNNO, G ;

NICOLO, F ;

JULVE, M .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 (06) :1049-1052

[4] USE OF ISOPOTENTIAL POINTS TO ELUCIDATE ION-EXCHANGE REACTION-MECHANISMS - CR(BPY)3(3)+ AT MONTMORILLONITE CLAY-MODIFIED ELECTRODES [J].

EDENS, GJ ;

FITCH, A ;

LAVYFEDER, A .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 307 (1-2) :139-154

[5] ON THE STRUCTURE OF 2,2'-BIPYRIMIDINE - GAS AND SOLID-PHASE STRUCTURE AND BARRIER TO INTERNAL-ROTATION [J].

FERNHOLT, L ;

ROMMING, C ;

SAMDAL, S .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1981, 35 (09) :707-715

[6]

Johnson C. K., 1976, ORNL5138

[7] CONDUCTIVITY OF CLAY-MODIFIED ELECTRODES - ALKALI-METAL CATION HYDRATION AND FILM PREPARATION EFFECTS [J].

LEE, SA ;

FITCH, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (12) :4998-5004

[8] TETRAAQUABIS(META-CHLOROBENZOATO)NICKEL(II) [J].

PAVKOVIC, SF ;

WILHELM, FC ;

BROWN, JN .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (APR) :1337-1340

[9] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473

[10]

SHELDRICK GM, 1993, SHELXL93 PROGRAM REF