Diamagnetic-paramagnetic conversion of tris(2-pyridylthio)methylcopper(II) through a structural change from trigonal bipyramidal to octahedral

被引：49

作者：

Santo, Ryoko

Miyamoto, Riichi

Tanaka, Rika

Nishioka, Takanori

Sato, Kazunobu

Toyota, Kazuo

Obata, Makoto

Yano, Shigenobu

Kinoshita, Isamu

Ichimura, Akio

Takui, Takeji

机构：

[1] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Osaka 5588585, Japan

[2] Nara Womens Univ, Grad Sch Human Culture, Div Mat Sci, Nara 6308506, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 45期

关键词：

copper; density functional calculations; electrochemistry; N ligands; oxidation;

D O I：

10.1002/anie.200603127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

All change: The stable, diamagnetic, trigonal-bipyramidal CuIII complex (see picture) arising from one-electron oxidation of a CuII complex undergoes conversion into a paramagnetic octahedral CuIII complex upon addition of Cl- ions. Characterization of the complexes and density functional calculations indicate that the initial one-electron oxidation is metal-rather than ligand-centered. (Chemical Equation Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：7611 / 7614

页数：4

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