Pyrolysis of the Moroccan (Tarfaya) oil shales under microwave irradiation

被引:175
作者
El harfi, K
Mokhlisse, A
Chanâa, MB
Outzourhit, A
机构
[1] Univ Caddi Ayyad, Chim Phys Lab, Fac Sci Marrakech, Semlalia 40001, Morocco
[2] Univ Caddi Ayyad, Lab Phys Solide & Couches Minces, Fac Sci Marrakech, Semlalia 40001, Morocco
关键词
pyrolysis; microwave; oil shales; shale oil;
D O I
10.1016/S0016-2361(99)00209-4
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The pyrolysis studies of the Tarfaya (Morocco) oil shales were performed using an installation specially adapted to the pyrolysis of oil shale under microwave irradiation. The microwave cavity and the reactor were designed to assure a good transfer of the microwave energy to the material and, to study the pyrolysis of the oil shales. The results obtained revealed that this process can be efficiently used for the purpose. The formation of oil seems related to the dehydration of the shale and to the relaxation of pyrite and the products of the degradation of the kerogen. Ln addition, the obtained oil has interesting characteristics. It is more maltenic, less polar and contains less sulfur and nitrogen than the oils obtained by conventional pyrolysis. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:733 / 742
页数:10
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