Control of reversible ligand insertion via supramolecular interactions in the solid state

被引:9
作者
Bowmaker, Graham A. [1 ]
Hanna, John V. [2 ]
Skelton, Brian W. [3 ]
White, Allan H. [3 ]
机构
[1] Univ Auckland, Dept Chem, Private Bag 92019, Auckland, New Zealand
[2] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
[3] Univ Western Australia, Sch Biomed Biomol & Chem Sci, Crawley, WA 6009, Australia
关键词
CRYSTAL-STRUCTURES; VIBRATIONAL-SPECTRA; THIOUREA; COMPLEXES; ADDUCTS; SALTS;
D O I
10.1039/b909055j
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reversible insertion of a ligand molecule into the coordination sphere of a metal complex in the solid state by variation of associated supramolecular hydrogen-bonding interactions in the solid is demonstrated in studies of complexes of copper(I) nitrate with thiourea.
引用
收藏
页码:5447 / 5449
页数:3
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