Direct synthesis and crystal structure of a mixed-valence copper complex

被引：30

作者：

Kovbasyuk, LA ^{[1
]}

Babich, OA ^{[1
]}

Kokozay, VN ^{[1
]}

机构：

[1] KIEV SHEVCHENKO UNIV,DEPT CHEM,UA-252033 KIEV,UKRAINE

来源：

POLYHEDRON | 1997年 / 16卷 / 01期

关键词：

mixed-valence complex; copper; direct synthesis; X-ray structure;

D O I：

10.1016/0277-5387(96)00224-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mixed-valence complex [Cu-II(DMF)(4)][Cu-4(I)(SCN)(4)(CN)(2)] (DMF = N,N-dimethylformamide) has been synthesized using a direct method of interaction and characterized by X-ray crystallography. The complex consists of layers formed by polymeric [Cu-4(I)(SCN)(4)(CN)(2)](2-)(n) anions and the [Cd-II(DMF)(4)](2+) cations disposed between anionic layers. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：161 / 163

页数：3

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