On/off regulation of catalysis by allosteric control of metal complex nuclearity

被引：38

作者：

Kovbasyuk, L

Pritzkow, H

Krämer, R

Fritsky, IO

机构：

[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

[2] Natl Taras Shevchenko Univ, Dept Chem, UA-01033 Kiev, Ukraine

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 07期

关键词：

D O I：

10.1039/b316225g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The nature of the allosteric metal ion M (Pd2+ or Pt2+) in complexes ML of a polytopic ligand controls uptake of additional Cu2+ ions; while [Cu2Pd(L-4H)(2+) is a highly active catalyst for phosphodiester cleavage, [CuPt(L-4H)] is inactive.

引用

页码：880 / 881

页数：2

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