A proposal for parametrizing the Sanchez-Lacombe equation of state

被引:35
作者
Gauter, K [1 ]
Heidemann, RA [1 ]
机构
[1] Univ Calgary, Dept Chem & Petr Engn, Calgary, AB T2N 1N4, Canada
关键词
D O I
10.1021/ie990800m
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
It is shown that the three pure-component parameters in the Sanchez-Lacombe equation of state can be determined from the critical temperature, critical pressure, and acentric factor. Vapor pressures from the equation have accuracy comparable to that obtained with the original Soave-Redlich-Kwong equation and Peng-Robinson equation, even without introducing any temperature dependence in the parameters. If temperature dependence is added to the Sanchez-Lacombe epsilon energy parameter, the accuracy in the vapor pressures can be improved.
引用
收藏
页码:1115 / 1117
页数:3
相关论文
共 16 条
[1]   THERMODYNAMIC PROPERTIES OF ORGANIC OXYGEN COMPOUNDS .37. VAPOR-PRESSURES OF METHANOL, ETHANOL, PENTAN-1-OL, AND OCTAN-1-OL FROM NORMAL BOILING TEMPERATURE TO CRITICAL-TEMPERATURE [J].
AMBROSE, D ;
SPRAKE, CHS ;
TOWNSEND, R .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1975, 7 (02) :185-190
[2]  
Ambrose D., 1970, J. Chem. Thermodyn., V2, P631, DOI [10.1016/0021-9614(70)90038-8, 10.1016/0021-]
[3]  
Angus S., 1976, INT THERMODYNAMIC TA
[4]  
Canjar L.N., 1967, Thermodynamic Properties and Reduced Correlations For Gases
[5]   PSRK - A GROUP CONTRIBUTION EQUATION OF STATE BASED ON UNIFAC [J].
HOLDERBAUM, T ;
GMEHLING, J .
FLUID PHASE EQUILIBRIA, 1991, 70 (2-3) :251-265
[6]   Polymer-solvent phase behavior near the solvent vapor pressure [J].
Koak, N ;
Heidemann, RA .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (11) :4301-4309
[7]   STATISTICAL THERMODYNAMICS OF FLUID MIXTURES [J].
LACOMBE, RH ;
SANCHEZ, IC .
JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (23) :2568-2580
[8]   A VERSATILE PHASE-EQUILIBRIUM EQUATION OF STATE [J].
MATHIAS, PM .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1983, 22 (03) :385-391
[9]   A CONSISTENT CORRECTION FOR REDLICH-KWONG-SOAVE VOLUMES [J].
PENELOUX, A ;
RAUZY, E ;
FREZE, R .
FLUID PHASE EQUILIBRIA, 1982, 8 (01) :7-23
[10]   A New Two-Constant Equation of State [J].
PENG, D ;
ROBINSON, DB .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1976, 15 (01) :59-64