Large melting-point hysteresis of Ge nanocrystals embedded in SiO2

被引:113
作者
Xu, Q. [1 ]
Sharp, I. D.
Yuan, C. W.
Yi, D. O.
Liao, C. Y.
Glaeser, A. M.
Minor, A. M.
Beeman, J. W.
Ridgway, M. C.
Kluth, P.
Ager, J. W., III
Chrzan, D. C.
Haller, E. E.
机构
[1] Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA
[2] Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA
[3] Lawrence Berkeley Natl Lab, Natl Ctr Electron Microscopy, Berkeley, CA 94720 USA
[4] Australian Natl Univ, Dept Elect Mat Engn, Res Sch Phys Sci & Engn, Canberra, ACT 0200, Australia
关键词
D O I
10.1103/PhysRevLett.97.155701
中图分类号
O4 [物理学];
学科分类号
0702 [物理学];
摘要
The melting behavior of Ge nanocrystals embedded within SiO2 is evaluated using in situ transmission electron microscopy. The observed melting-point hysteresis is large (+/- 17%) and nearly symmetric about the bulk melting point. This hysteresis is modeled successfully using classical nucleation theory without the need to invoke epitaxy.
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收藏
页数:4
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