Electronic sputtering analysis of astrophysical ices

Experimental results on fast ion collision with icy surfaces having astrophysical interest are presented. Cf-252 fission fragments projectiles were used to induce ejection of ionized material from H2O, CO2, CO, NH3, N-2, O-2 and Ar ices; the secondary ions were identified by time-of-flight mass spectrometry. It is observed that all the bombarded frozen gas targets emit cluster ions which have the structure XnR+/-, where X is the neutral ice molecule and R+/- is either an atomic or a molecular ion. The shape of the positive or negative ion mass spectra is characterized by a decreasing yield as the emitted ion mass increases and is generally described by the sum of two exponential functions. The positive ion water ice spectrum is dominated by the series (H2O)(n)H3O+ and the negative ion spectrum by the series (H2O)(n)OH- and (H2O)(n)O-. The positive ion CO2 ice spectrum is characterized by R+ = C+, O+, CO+, O-2(+) or CO2+ and the negative one by R- = CO3-. The dominant series for ammonia ice correspond to R+ = NH4+ and to R- = NH2-. The oxygen series are better described by (O-3)(n)O-m(+) secondary ions where m = 1, 2 or 3. Two positive ion series exist for N-2 ice: (N-2)(n)N-2(+) and (N-2)(n)N+. For argon positive secondary ions, only the (Ar)(n)Ar+ series was observed. Most of the detected molecular ions were formed by one-step reactions. Ice temperature was varied from similar to 20 K to complete sublimation.