Intramolecular Diels-Alder reactions of alkenylboranes - A stereoselective route to functionalized bicyclo[4.3.0]nonenes.

被引：19

作者：

Batey, RA

Lin, D

Wong, A

Hayhoe, CLS

机构：

[1] Department of Chemistry, Lash Miller Laboratories, University of Toronto, Toronto, Ont., M5S 3H6

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 21期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0040-4039(97)00716-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A one-pot procedure for the synthesis of bicyclo[4.3.0] alkenols is described. Alkenylboranes, formed in situ by hydroboration, undergo stereoselective intramolecular Diels-Alder reactions to give alkylboranes, which upon oxidation, yield the products corresponding to endo addition. (C) 1997 Elsevier Science Ltd.

引用

页码：3699 / 3702

页数：4

共 24 条

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