Cross-metathesis between ethane and toluene catalyzed by [(SiO)2TaH]:: the first example of a cross-metathesis reaction between an alkane and an aromatic

被引:23
作者
Taoufik, M
Schwab, E
Schultz, M
Vanoppen, D
Walter, M
Thivolle-Cazat, J
Basset, JM
机构
[1] ESCPE Lyon, CNRS, UMR 9986, Lab Chim Organomet Surface, F-69626 Villeurbanne, France
[2] BASF AG, D-67056 Ludwigshafen, Germany
关键词
D O I
10.1039/b403166k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The silica-supported tantalum hydride [(dropSiO)(2)TaH] 1 catalyzes at moderate temperature (150-250degreesC) the cross-metathesis reaction between toluene and ethane, to form mainly ethylbenzene and xylenes.
引用
收藏
页码:1434 / 1435
页数:2
相关论文
共 18 条
[1]  
BASF, Patent No. 10100485
[2]  
Copéret C, 2001, ANGEW CHEM INT EDIT, V40, P2331, DOI 10.1002/1521-3773(20010618)40:12<2331::AID-ANIE2331>3.0.CO
[3]  
2-P
[4]   THE ORGANOMETALLIC CHEMISTRY OF ALKANES [J].
CRABTREE, RH .
CHEMICAL REVIEWS, 1985, 85 (04) :245-269
[5]   ASPECTS OF METHANE CHEMISTRY [J].
CRABTREE, RH .
CHEMICAL REVIEWS, 1995, 95 (04) :987-1007
[6]   ACTINACYCLOBUTANES - IMPLEMENTATION OF THERMOCHEMICALLY BASED STRATEGIES FOR THE RING-OPENING STOICHIOMETRIC C-H FUNCTIONALIZATION OF SATURATED AND OLEFINIC HYDROCARBONS [J].
FENDRICK, CM ;
MARKS, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (03) :425-437
[7]   THERMOCHEMICALLY BASED STRATEGIES FOR C-H ACTIVATION ON SATURATED-HYDROCARBON MOLECULES - RING-OPENING REACTIONS OF A THORACYCLOBUTANE WITH TETRAMETHYLSILANE AND METHANE [J].
FENDRICK, CM ;
MARKS, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (07) :2214-2216
[8]  
Maury O, 1999, ANGEW CHEM INT EDIT, V38, P1952, DOI 10.1002/(SICI)1521-3773(19990712)38:13/14<1952::AID-ANIE1952>3.0.CO
[9]  
2-V
[10]  
Olah G.A., 1963, FREIDEL CRAFTS REL