Biologically active metabolites from fungi .9. New palmarumycins CP4a, and CP5 from Coniothyrium palmarum: Structure elucidation, crystal structure analysis and determination of the absolute configuration by CD calculations

被引:43
作者
Krohn, K
Beckmann, K
Florke, U
Aust, HJ
Draeger, S
Schulz, B
Busemann, S
Bringmann, G
机构
[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST MIKROBIOL,D-38106 BRAUNSCHWEIG,GERMANY
[2] UNIV WURZBURG,INST ORGAN CHEM,D-97074 WURZBURG,GERMANY
关键词
D O I
10.1016/S0040-4020(97)00066-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Two new palmarumycins CP4a (2) and CP5 (3) with an unusual bridged structure were isolated from Coniothyrium palmarum. The structure and relative configuration was elucidated by NMR and X-ray studies; the absolute configuration was determined by CD calculations. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:3101 / 3110
页数:10
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