1,1-bis(3',4,4'-trimethyltetrathiafulvalen-3-yl)ethanol ethanol hemisolvate; A new bifunctional pi-donor molecule

被引：3

作者：

Dolbecq, A

Fourmigue, M

Batail, P

机构：

[1] Inst. des Matériaux de Nantes, UMR 110, Université de Nantes, 44072 Nantes Cedex 03

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196000509

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound {1,1-bis[2-(4,5-dimethyl-1,3-dithiol-2-ylidene)-5-methyl-1,3-dithiol-4-yl]ethanol ethanol hemisolvate, C20H22OS8.0.5C(2)H(5)OH} contains bridged tetrathiafulvalene (TTF) molecules. The two TTF moieties of the bifunctional donor are quasi-orthogonal. Donor layers and hydrogen-bonded solvent layers alternate along the c axis.

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页码：1543 / 1545

页数：3

相关论文

共 11 条

[1] GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].

CREMER, D ;

POPLE, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358

[2]

CREMER D, 1979, RING COORDINATE TRAN

[3]

DUNITZ JD, 1978, XRAY ANAL STRUCTURE, P425

[4]

GINSBURG D, 1975, MONOGRAPHS MODERN CH, V7

[5] PROPELLANES .79. COMPARISON OF THE GEOMETRIES OF DITHIA[1.3.3]PROPELLANES DITHIA[2.3.3], DITHIA[3.3.3] AND DITHIA(AND OXATHIA)[4.3.3]PROPELLENES - STUDY OF THE INFLUENCE OF COMPLEXATION WITH HGC12, I2, CDC12 AND PDC12 AND OF FORMATION OF SULFOXIDES ON SOME OF THESE COMPOUNDS - DEMONSTRATION OF THE KLAMMER EFFECT STRUCTURES OF 18 CRYSTALSE [J].

HERBSTEIN, FH ;

ASHKENAZI, P ;

KAFTORY, M ;

KAPON, M ;

REISNER, GM ;

GINSBURG, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1986, 42 :575-601

[6]

JOHNSON CK, 1965, ORNL3794

[7] PROPELLANES .83. SOLID-STATE CONFORMATIONS OF SEVERAL SUBSTITUTED TRIAZA-[3.3.3]PROPELLANES AND OF AN OXADIAZA[3.3.3]PROPELLANE [J].

KAPON, M ;

KAFTORY, M ;

KNOWLES, P ;

WEINBERG, O ;

GINSBURG, D .

HETEROCYCLES, 1987, 25 :11-12

[8] PARST - A SYSTEM OF FORTRAN ROUTINES FOR CALCULATING MOLECULAR-STRUCTURE PARAMETERS FROM RESULTS OF CRYSTAL-STRUCTURE ANALYSES [J].

NARDELLI, M .

COMPUTERS & CHEMISTRY, 1983, 7 (03) :95-98

[9]

SHELDRICK G, 1993, SHELXL93 PROGRAM CRY

[10] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473