Aqueous supramolecular polymer formed from an amphiphilic perylene derivative

被引：77

作者：

Arnaud, A

Belleney, J

Boué, F

Bouteiller, L

Carrot, G

Wintgens, W

机构：

[1] Univ Paris 06, UMR 7610, Lab Chim Polymeres, F-75252 Paris 05, France

[2] Lab Rech Polymeres, F-94320 Thiais, France

[3] CEA Saclay, Lab Leon Brillouin, F-91191 Gif Sur Yvette, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 13期

关键词：

arenes; pi interactions; polymers; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200353434

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aromatic stacking and hydrophobic interactions are the driving forces for the reversible self-assembly of an amphiphilic perylene derivative in water to form a linear polymer (see schematic representation). The structure of the assemblies has been elucidated by small-angle neutron scattering, and the association strength determined by NMR and fluorescence spectroscopies.

引用

收藏

页码：1718 / 1721

页数：4

相关论文

共 17 条

[1] PHASE-BEHAVIOR AND STRUCTURE OF A NONIONIC DISCOIDAL AMPHIPHILE IN WATER [J].

BODEN, N ;

BUSHBY, RJ ;

HARDY, C ;

SIXL, F .

CHEMICAL PHYSICS LETTERS, 1986, 123 (05) :359-364

[2] Chirality amplification in dynamic helical columns in water [J].

Brunsveld, L ;

Lohmeijer, BGG ;

Vekemans, JAJM ;

Meijer, EW .

CHEMICAL COMMUNICATIONS, 2000, (23) :2305-2306

[3] Hierarchical formation of helical supramolecular polymers via stacking of hydrogen-bonded pairs in water [J].

Brunsveld, L ;

Vekemans, JAJM ;

Hirschberg, JHKK ;

Sijbesma, RP ;

Meijer, EW .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4977-4982

[4] Supramolecular polymers [J].

Brunsveld, L ;

Folmer, BJB ;

Meijer, EW ;

Sijbesma, RP .

CHEMICAL REVIEWS, 2001, 101 (12) :4071-4097

[5]

Ciferri A, 2000, SUPRAMOLECULAR POLYMERS, P1

[6] Mechanism of supramolecular polymerizations (Reprinted from Supramolecular Polymers, pg 1-59, 2000) [J].

Ciferri, A .

JOURNAL OF MACROMOLECULAR SCIENCE-POLYMER REVIEWS, 2003, C43 (02) :271-322

[7] CHIRAL MICELLAR PORPHYRIN FIBERS WITH 2-AMINOGLYCOSAMIDE HEAD GROUPS [J].

FUHRHOP, JH ;

DEMOULIN, C ;

BOETTCHER, C ;

KONING, J ;

SIGGEL, U .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) :4159-4165

[8] Supramolecular polymers formed by modified cyclodextrins [J].

Harada, A ;

Kawaguchi, Y ;

Hoshino, T .

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2001, 41 (1-4) :115-121

[9] Structural and rheological study of a bis-urea based reversible polymer in an apolar solvent [J].

Lortie, F ;

Boileau, S ;

Bouteiller, L ;

Chassenieux, C ;

Demé, B ;

Ducouret, G ;

Jalabert, M ;

Lauprêtre, F ;

Terech, P .

LANGMUIR, 2002, 18 (19) :7218-7222

[10] Comparisons of indefinite self-association models [J].

Martin, RB .

CHEMICAL REVIEWS, 1996, 96 (08) :3043-3064