Effects of aromatic spacers on the properties of organic field effect transistors based on π-extended tetrathiafulvalene derivatives

被引:22
作者
Aleveque, Olivier [1 ]
Frere, Pierre [1 ]
Leriche, Philippe [1 ]
Breton, Tony [1 ]
Cravino, Antonio [1 ]
Roncali, Jean [1 ]
机构
[1] Univ Angers, CNRS, CIMA, UMR 6200, F-49045 Angers, France
关键词
THIN-FILM TRANSISTORS; FUSED BIS(TETRATHIAFULVALENE) COMPOUNDS; DITHIOPHENE-TETRATHIAFULVALENE; HIGH-PERFORMANCE; HIGH-MOBILITY; SEMICONDUCTORS; ANALOGS; TTF; 1,2-BIS(1,4-DITHIAFULVEN-6-YL)BENZENES; ELECTRONICS;
D O I
10.1039/b822159f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
OFETs built from extended TTF derivatives containing N-methylpyrrole, furan, thiophene and benzene with meta or para linkages as spacers are presented. The aromatic spacer plays a crucial role in the characteristics and stability of the OFETs. The less conjugated derivative with a meta-benzene moiety as spacer has the best mobility, with a higher on/off ratio and strongly enhanced stability in air.
引用
收藏
页码:3648 / 3651
页数:4
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