Multielectron redox process of vanadium complexes in oxidation of low-coordinate vanadium(III) to oxovanadium(V) with dioxygen

被引：51

作者：

Oyaizu, K ^{[1
]}

Yamamoto, K ^{[1
]}

Yoneda, K ^{[1
]}

Tsuchida, E ^{[1
]}

机构：

[1] WASEDA UNIV,ADV RES INST SCI & ENGN,DEPT POLYMER CHEM,TOKYO 169,JAPAN

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 23期

关键词：

D O I：

10.1021/ic960198h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electroreduction of a vanadium dinuclear complex [(salen)V-IV-O-V-IV(salen)](2+) in the presence of Or resulted in the stoichiometric formation of a [(salen)V-IV-O-V-V-(salen)=O](+) complex. The process provided not only evidence for the interconversion of vanadium(III)/oxovanadium(V) in the action of vanadium complexes operating as redox catalysts, but also possibilities for the use of the vanadium complex as electrocatalysts for the 4-electron reduction of O-2.

引用

页码：6634 / &

页数：3

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