Ruthenium sulfophthalocyanine catalyst for the oxidation of chlorinated olefins with hydrogen peroxide

被引：27

作者：

Bressan, M

Celli, N

d'Alessandro, N

Liberatore, L

Morvillo, A

Tonucci, L

机构：

[1] Univ Chieti G Dannunzio, Dept Sci, I-65127 Pescara, Italy

[2] Consorzio Mario Negri Sud, G Paone Environm Hlth Ctr, I-66033 Santa Maria Imbaro, Italy

[3] Univ Padua, Dept Inorgan Chem, I-35100 Padua, Italy

[4] Ctr CNR, I-35100 Padua, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 593卷

关键词：

aqueous organometallic catalysis; chlorinated organics; hydrogen peroxide; ruthenium phthalocyanine; oxidation;

D O I：

10.1016/S0022-328X(99)00606-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In aqueous solution and at room temperature, various alpha-chloro-alkenes an effectively dechlorinated by hydrogen peroxide oxidation using a water-soluble ruthenium(II)-tetrasulfophthalocyanine catalyst, RuPcS. The molecular structure of RuPcS has been elucidated by ESI-mass spectroscopy. In the reaction conditions, and specifically in acidic media, the complex rapidly gives rise to a novel species, most likely catalytically active, whose nature is investigated. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：416 / 420

页数：5

共 19 条

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