Mo(W,V)-Cu(Ag)-S(Se) cluster compounds

被引：212

作者：

Hou, HW

Xin, XQ

Shi, S

机构：

[1] NANJING UNIV, DEPT CHEM, STATE KEY LAB COORDINAT CHEM, NANJING 210093, PEOPLES R CHINA

[2] NATL UNIV SINGAPORE, DEPT CHEM ENGN, OPT CRYSTAL LAB, SINGAPORE 117548, SINGAPORE

来源：

COORDINATION CHEMISTRY REVIEWS | 1996年 / 153卷

关键词：

Mo(W; V)-Cu(Ag)-S(Se) cluster compounds; preparation; skeletal structure; reactions; spectroscopic properties; non-linear optical properties;

D O I：

10.1016/0010-8545(95)01224-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review summarizes the preparation, skeletal structure, reactions, spectroscopic properties and nan-linear optical properties of Mo(W,V)-Cu(Ag)-S(Se) cluster compounds; 190 such compounds belong to 23 structural types; 25 reactions are classified into ligand substitution, addition and decomposition reactions. Recently, some Mo(W)-Cu(Ag)-S clusters were found to exhibit strong non-linear optical properties; the optical limiting threshold measured for [(PPh(3))(4)Ag4Mo2S8] is one order of magnitude lower than that of C-60.

引用

页码：25 / 56

页数：32

共 167 条

[1] PREPARATION, CRYSTAL-STRUCTURE, AND SPECTROSCOPIC STUDIES OF [NPRN4]2[(PHS)CUS2MOS2] AND [NPRN4]2[(PHS)CUS2MOS2CU(SPH)], CONTAINING BENZENETHIOLATOCOPPER(I) TETRATHIOMOLYBDATE(VI) COMPLEX ANIONS [J].