Pentadienyl ligands: Their properties, potential, and contributions to inorganic and organometallic chemistry

被引：99

作者：

Ernst, RD ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

COMMENTS ON INORGANIC CHEMISTRY | 1999年 / 21卷 / 4-6期

基金：

美国国家科学基金会;

关键词：

pentadienyl; metallocene; open metallocene;

D O I：

10.1080/02603599908012010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pentadienyl ligands have been found to possess many unique and potentially useful characteristics, including the ability to adopt a wide variety of eta(1), eta(3), and eta(5) bonding modes, a propensity for bonding to metals in low oxidation states, a tendency toward forming sterically crowded complexes, and the ability to engage in a wide variety of coupling reactions, even while being more strongly bound to a metal center than the ubiquitous cyclopentadienyl Ligand. The combination of these properties has led to a rich body of chemistry for these ligands, and the promise that much more remains to be gained.

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收藏

页码：285 / 325

页数：41

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