Electron scattering in cooled HCl:: boomerang structures and outer-well resonances in elastic and vibrational excitation cross sections

被引:34
作者
Allan, M [1 ]
Cízek, M
Horácek, J
Domcke, W
机构
[1] Univ Fribourg, Inst Phys Chem, Perolles, CH-1700 Fribourg, Switzerland
[2] Charles Univ Prague, Fac Math & Phys, Dept Theoret Phys, CR-18000 Prague 8, Czech Republic
[3] Tech Univ Munich, Inst Phys & Theoret Chem, D-85747 Garching, Germany
关键词
D O I
10.1088/0953-4075/33/6/103
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Differential cross sections for elastic scattering and excitation of the nu = 1 vibrational level have been measured for rotationally cooled HCl at energies near the threshold for dissociative attachment. The cooling improves the visibility of the oscillatory structure in the nu = 0 --> 1 cross section and permits the observation of a similar structure also in the elastic channel. The integral nu = 0 --> 1 cross section and the resonant part of the integral elastic cross section have been calculated using a nonlocal resonance model. A high degree of agreement of the details of the measured and calculated structures confirms the correctness of the model and the high accuracy of the nb initio HCl(-) potential-energy function used as input to the model.
引用
收藏
页码:L209 / L213
页数:5
相关论文
共 24 条
[1]   Measurement of absolute differential cross sections for vibrational excitation of O-2 by electron impact [J].
Allan, M .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1995, 28 (23) :5163-5175
[2]   MEASUREMENT OF DIFFERENTIAL CROSS-SECTIONS FOR EXCITATION OF HELIUM BY ELECTRON-IMPACT WITHIN THE 1ST 4 EV ABOVE THRESHOLD [J].
ALLAN, M .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1992, 25 (07) :1559-1575
[3]   A BOUND HCL- SPECIES - AN ABINITIO QUANTUM-CHEMICAL STUDY [J].
ASTRAND, PO ;
KARLSTROM, G .
CHEMICAL PHYSICS LETTERS, 1990, 175 (06) :624-628
[4]   CONFIGURATION INTERACTION IN CONTINUUM STATES OF MOLECULES [J].
BARDSLEY, JN .
JOURNAL OF PHYSICS PART B ATOMIC AND MOLECULAR PHYSICS, 1968, 1 (03) :349-&
[5]   THRESHOLD STRUCTURE IN ELASTIC CROSS-SECTION FOR SCATTERING OF SLOW-ELECTRONS FROM HCL AND HBR [J].
BURROW, PD .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1974, 7 (13) :L385-L388
[6]   Associative detachment, dissociative attachment, and vibrational excitation of HCl by low-energy electrons [J].
Cízek, M ;
Horácek, J ;
Domcke, W .
PHYSICAL REVIEW A, 1999, 60 (04) :2873-2881
[7]  
CVEJANOVIC S, 1989, 3 EUR C AT MOL PHYS, P638
[8]  
CVEJANOVIC S, 1993, AIP C P, V295, P390
[9]  
DOMCKE W, 1990, AIP CONF PROC, V204, P169, DOI 10.1063/1.39189
[10]   THEORY OF RESONANCE AND THRESHOLD EFFECTS IN ELECTRON MOLECULE COLLISIONS - THE PROJECTION-OPERATOR APPROACH [J].
DOMCKE, W .
PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 1991, 208 (02) :97-188