Access to the structures of fluoromagnesium compounds:: synthesis and structural characterization of the β-diketiminato magnesium fluoride [{CH(CMeNAr)2}Mg(μ-F)(THF)]2•toluene

被引：38

作者：

Hao, HJ ^{[1
]}

Roesky, HW ^{[1
]}

Ding, YQ ^{[1
]}

Cui, CM ^{[1
]}

Schormann, M ^{[1
]}

Schmidt, HG ^{[1
]}

Noltemeyer, M ^{[1
]}

Zemva, B ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2002年 / 115卷 / 02期

关键词：

magnesium; fluorides; beta-diketiminato ligands; bischelating figands;

D O I：

10.1016/S0022-1139(02)00043-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

beta-Diketiminato magnesium fluoride [{CH(CMeNAr)(2)}Mg(mu-F)(THF)](2)(.)toluene (Ar = 2,6-i-Pr2C6H3, 2(.)toluene) was synthesized. The molecular structure of 2 revealed for the first time, the double fluoro bridge feature between the two magnesium atoms with a typical Mg-F bond length (average 1.95 Angstrom). (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：143 / 147

页数：5

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