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Metal-chelating capacities attached to fullerenes

被引：112
作者：
Meijer, MD [1 ]
van Klink, GPM [1 ]
van Koten, G [1 ]
机构：
[1] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands
来源：
COORDINATION CHEMISTRY REVIEWS | 2002年 / 230卷 / 1-2期
关键词：
fullerenes; C-60; bucky-ligands; artificial photosynthesis; metal complexes; porphyrines; macromolecular synthesis;
D O I：
10.1016/S0010-8545(01)00456-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review describes. the synthesis, properties and application of fullerenes covalently attached to metal-chelating groups. The application of these structures in artificial photosynthetic systems and their reaction on external stimuli, such as light or electrons is described. Furthermore, the use of fullerene organometallic building blocks in macromolecular synthesis and catalysis has been highlighted. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码：141 / 163
页数：23
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