Interannual controls on Weddell Sea surface water fCO2 during the autumn-winter transition phase

The fugacity of carbon dioxide (fCO(2)) of the surface waters of the Weddell Sea along the prime meridian has been described for the austral autumn in 1996 and 1998. For individual years, fCO(2) has a strong linear relationship with sea surface temperature, although the relationships cannot be reconciled to provide an interannually consistent algorithm for remotely sensed assessment of fCO(2). However, from the assumption that Weddell Sea surface water has a single end member (upwelled Warm Deep Water) we have determined the relative contributions of heating, ice-melt, and biological activity on fCO(2). A breakdown of the controls shows that the measured annual fCO(2) distributions can be recreated for both transects by adjusting solely for thermodynamic forcing, and model adjustments for salinity are small except in regions of significant upwelling during 1998. The incorporation of nitrate utilisation into the model results in a general and significant underestimation of fCO(2). This runs contrary to the earlier findings of Sabine and Key (Mar. Chem. 60 (1998) 95) in the Southern Ocean although it is consistent with models in the area (Louanchi et al., Deep-Sea Res. 148 (2001) 1581). A major caveat to these findings is the significant departure of the thermodynamic model and a tightening of the nitrate-adjusted model in 1998 in areas with deeper mixing in the southern Weddell Sea. We propose that there are two reasons for the discrepancies in our model: the source waters are not as homogenous as the model assumes; and there are geographical and seasonal variations of CO2 exchange with the atmosphere and the input of inorganic carbon and nitrate from below the mixed layer resulting in imbalances in the mixed layer concentration ratios. (C) 2004 Elsevier Ltd. All rights reserved.