A study on the cycle performance of lithium secondary batteries using lithium nickel-cobalt composite oxide and graphite/coke hybrid carbon

10 Wh-class (30650 type) lithium secondary batteries Acre fabricated using LiNi0.7Co0.3O2 as the positive electrode material and graphite coke hybrid carbon as the negative electrode material. In our previous work, we found that LiNi0.7Co0.3O2 and graphite coke hybrid carbon each provide a longer cycle life among several candidates (Kida et al. J. Power Sources 94 (2001) 74: Kida et al., in preparation: Kinoshita et al., J. Power Sources 102 (2001) 284). In this study, the cycle performance of cells using both LiNi0.7Co0.3O2 and graphite coke hybrid carbon was examined and the deterioration factor of the discharge capacity was investigated during charge discharge tests. We then focused our interest on the negative electrode and analyzed it using Li-7 nuclear magnetic resonance (NMR) spectroscopy. X-ray photoelectron spectroscopy (XPS). and electrochemical impedance spectroscopy (EIS). After the discharge capacity of the battery deteriorated to 70% of the rated capacity after 2000 cycles, the graphite coke hybrid carbon showed 91% of initial discharge capacity. When the solid electrolyte interface (SEI) (LiF, Li2CO3 and polymers) (E. Peled, J. Electrochem. Soc. 126 (1979) 2047) on the carbon negative electrode became thicker in the charge,discharge cycle test, the impedance was considered to ha, e increased. This suggests that the deterioration of the graphite coke hybrid carbon material is not so large, but that the production of the SEI on the negative electrode and impedance change of the negative electrode are factors of the capacity fade, (C) 2002 Elsevier Science Ltd. All rights reserved.