Bismuth alkoxides. The first structurally-characterized bismuth-transition metal heterobimetallic alkoxide: [BiCl3OV(OC2H4OCH3)(3)](2)

被引：42

作者：

Pell, JW ^{[1
]}

Davis, WC ^{[1
]}

zurLoye, HC ^{[1
]}

机构：

[1] MIT, DEPT CHEM, CAMBRIDGE, MA 02139 USA

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 20期

关键词：

D O I：

10.1021/ic9604122

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of BiCl3 and VO(OiPr)3 in 2-methoxyethanol resulted in the formation of the first bismuth-transition metal bimetallic alkoxide, [BiCl3(mu-O)(mu-OC2H4OCH3)(2)(OC2H4OCH3)V](2). The vanadium atom is in an unusual distorted octahedral coordination environment, while the coordination around the bismuth is best described as an octrahedron capped by a long bonded interaction with an oxygen atom. There does not appear to be a stereochemically-active lone pair present on the bismuth atom.

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页码：5754 / +

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