Total synthesis of (+)-preussin: Control of the stereogenic centers by enantioselective allyltitanations

被引:14
作者
Canova, S [1 ]
Bellosta, V [1 ]
Cossy, J [1 ]
机构
[1] Ecole Super Phys & Chim Ind Ville Paris, Chim Organ Lab, CNRS, F-75231 Paris 05, France
关键词
preussin; allyltitanation; cross-metathesis;
D O I
10.1055/s-2004-829564
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
(+)-Preussin was synthesized in ten steps with an overall yield of 6.4% from phenylacetaldehyde. The three stereogenic centers were controlled by enantioselective allyltitanations of aldehydes.
引用
收藏
页码:1811 / 1813
页数:3
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