Fluoroacrylate-bound fluorous-phase soluble hydrogenation catalysts

被引:39
作者
Bergbreiter, DE [1 ]
Franchina, JG [1 ]
Case, BL [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
关键词
D O I
10.1021/ol991352h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Fluoroacrylate polymer-bound hydrogenation catalysts are described, N-Acryloxysuccinimide-containing fluoroacrylate polymers were converted into phosphine ligands and subsequently into analogues of Wilkinson's catalyst by amidation of N-acryloxysuccinimide active ester residues and Rh exchange. The resulting catalysts have excellent activity and can be reused following fluorous biphasic liquid/liquid separation and extraction.
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页码:393 / 395
页数:3
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