Synthesis and characterization of zinc titanate nano-crystal powders by sol-gel technique

被引：145

作者：

Chang, YS

Chang, YH ^{[1
]}

Chen, IG

Chen, GJ

Chai, YL

机构：

[1] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 70101, Taiwan

[2] Dahan Inst Technol, Dept Resources Engn, Hualien 971, Taiwan

[3] I Shou Univ, Dept Mat Sci & Engn, Kaohsiung, Taiwan

来源：

JOURNAL OF CRYSTAL GROWTH | 2002年 / 243卷 / 02期

关键词：

nanostructures; X-ray diffraction; growth from solutions; oxides; titanium compounds; zinc compounds;

D O I：

10.1016/S0022-0248(02)01490-2

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A sol-gel technique including the Pechim process has been employed for the preparation of nano-sized zinc titanate (ZnTiO3) powders. The yielding powders were heated at temperature from 500degreesC to 1000degreesC for various times. The ZnTiO3 phase was formed at the beginning of 500degreesC. The shape of crystalline will be changed from granular to fiber as the calcination temperature increasing from 800degreesC to 1000degreesC. The activation energy of crystallization of ZnTiO3 is 172.74 kJ/moI calculated from Kissinger's equation. The activation energy of grain growth is 20.83 kJ/moI experimented by Arrhenius equation. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：319 / 326

页数：8

共 19 条

[1] COMPOUND FORMATION AND CRYSTAL STRUCTURE IN THE SYSTEM ZNO-TIO2 [J].