Waterborne, nanocomposite pressure-sensitive adhesives with high tack energy, optical transparency, and electrical conductivity

被引:119
作者
Wang, Tao
Lei, Chun-Hong
Dalton, Alan B.
Creton, Costantino
Lin, Yi
Shiral Fernando, K. A.
Sun, Ya-Ping
Manea, Mihaela
Asua, Jose M.
Keddie, Joseph L. [1 ]
机构
[1] Univ Surrey, Dept Phys, Guildford GU2 7XH, Surrey, England
[2] Univ Surrey, UniS Mat Inst, Guildford GU2 7XH, Surrey, England
[3] ESPCI, Lab PPMD, F-75231 Paris 05, France
[4] Clemson Univ, Dept Chem, Clemson, SC 29634 USA
[5] Clemson Univ, Lab Emerging Mat & Technol, Clemson, SC 29634 USA
关键词
D O I
10.1002/adma.200601335
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Transparent and conductive pressure-sensitive adhesives are cast from aqueous colloidal dispersions of poly(butyl acrylate) (P(BuA)) and functionalized carbon nanotubes (CNTs). At the percolation threshold for network formation (at only 0.3 wt % functionalized CNT), the nanotubes remarkably double the amount of strain at adhesive failure and increase the adhesion energy by 85 % (see figure). The tack properties are explained by current models of adhesive debonding.
引用
收藏
页码:2730 / +
页数:6
相关论文
共 34 条
[1]   Improving water sensitivity in acrylic films using surfmers [J].
Aramendia, E ;
Barandiaran, MJ ;
Grade, J ;
Blease, T ;
Asua, JM .
LANGMUIR, 2005, 21 (04) :1428-1435
[2]   Cavity growth in soft adhesives [J].
Chiche, A ;
Dollhofer, J ;
Creton, C .
EUROPEAN PHYSICAL JOURNAL E, 2005, 17 (04) :389-401
[3]   Cavitation in adhesives [J].
Chikina, I ;
Gay, C .
PHYSICAL REVIEW LETTERS, 2000, 85 (21) :4546-4549
[4]   Deformation and failure modes of adhesively bonded elastic layers [J].
Crosby, AJ ;
Shull, KR ;
Lakrout, H ;
Creton, C .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (05) :2956-2966
[5]   Multiwalled carbon nanotube/polymer nanocomposites:: Processing and properties [J].
Dalmas, F ;
Chazeau, L ;
Gauthier, C ;
Masenelli-Varlot, K ;
Dendievel, R ;
Cavaillé, JY ;
Forró, L .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2005, 43 (10) :1186-1197
[6]   Processing and characterization of carbon nanotube/poly(styrene-co-butyl acrylate) nanocomposites [J].
Dufresne, A ;
Paillet, M ;
Putaux, JL ;
Canet, R ;
Carmona, F ;
Delhaes, P ;
Cui, S .
JOURNAL OF MATERIALS SCIENCE, 2002, 37 (18) :3915-3923
[7]   Theoretical and computational studies of carbon nanotube composites and suspensions: Electrical and thermal conductivity [J].
Foygel, M ;
Morris, RD ;
Anez, D ;
French, S ;
Sobolev, VL .
PHYSICAL REVIEW B, 2005, 71 (10)
[8]   Theory of tackiness [J].
Gay, C ;
Leibler, L .
PHYSICAL REVIEW LETTERS, 1999, 82 (05) :936-939
[9]   Adhesion of latex films. Part IV. Dominating interfacial effect of the surfactant [J].
Gerin, PA ;
Grohens, Y ;
Schirrer, R ;
Holl, Y .
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY, 1999, 13 (02) :217-236
[10]   Chain conformational transformations in syndiotactic polypropylene/layered silicate nanocomposites during mechanical elongation and thermal treatment [J].
Gregoriou, VG ;
Kandilioti, G ;
Bollas, ST .
POLYMER, 2005, 46 (25) :11340-11350