Preparation and characterization of [H3N(CH2)6NH3]PbI4 and similar compounds with a layered perovskite structure

被引：79

作者：

Mousdis, GA

Papavassiliou, GC

Raptopoulou, CP

Terzis, A

机构：

[1] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

[2] NCSR Demokritos, Inst Mat Sci, GR-15310 Athens, Greece

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2000年 / 10卷 / 02期

关键词：

D O I：

10.1039/a906161d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The preparation, crystal structure and optical absorption spectra of [H3N(CH2)(6)NH3]PbX4 (X = I, Br, Cl) and similar compounds based on Sn are described. The compounds [H3N(CH2)(6)NH3]PbX4 consist of ordered perovskite sheets of the corresponding-corner sharing PbX6 octahedra, which alternate with the H3N(CH2)(6)NH3 sheets. The excitonic peaks in the optical absorption spectra of these compounds occur at shorter wavelengths than those of the corresponding compounds with the formula [C6H5CH2CH2NH3](2)MX4.

引用

页码：515 / 518

页数：4

共 23 条

[1] PREPARATION AND CHARACTERIZATION OF LAYERED LEAD HALIDE COMPOUNDS
CALABRESE, J
JONES, NL
HARLOW, RL
HERRON, N
THORN, DL
WANG, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (06) : 2328 - 2330
[2] CRYSTAL-STRUCTURE AND PHASE-TRANSITION IN THE PEROVSKITE-TYPE LAYER MOLECULAR COMPOSITE NH3(CH2)4NH3PBCL4
COURSEILLE, C
CHANH, NB
MARIS, T
DAOUD, A
ABID, Y
LAGUERRE, M
[J]. PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1994, 143 (02): : 203 - 214
[3] Highly efficient electroluminescence from a heterostructure device combined with emissive layered-perovskite and an electron-transporting organic compound
Hattori, T
Taira, T
Era, M
Tsutsui, T
Saito, S
[J]. CHEMICAL PHYSICS LETTERS, 1996, 254 (1-2) : 103 - 108
[4] OPTICAL-PROPERTIES DUE TO ELECTRONIC-TRANSITIONS IN 2-DIMENSIONAL SEMICONDUCTORS (CNH2N + 1NH3)2PBI4
ISHIHARA, T
TAKAHASHI, J
GOTO, T
[J]. PHYSICAL REVIEW B, 1990, 42 (17): : 11099 - 11107
[5] EXCITON-STATE IN TWO-DIMENSIONAL PEROVSKITE SEMICONDUCTOR (C10H21NH3)2PBI4
ISHIHARA, T
TAKAHASHI, J
GOTO, T
[J]. SOLID STATE COMMUNICATIONS, 1989, 69 (09) : 933 - 936
[6] Ishihara T., 1995, OPTICAL PROPERTIES L, P288, DOI [DOI 10.1142/9789814261388_0006, 10.1142/9789814261388_0006]
[7] MAGNETOOPTICAL STUDY ON EXCITONIC SPECTRA IN (C6H13NH3)2PBI4
KATAOKA, T
KONDO, T
ITO, R
SASAKI, S
UCHIDA, K
MIURA, N
[J]. PHYSICAL REVIEW B, 1993, 47 (04): : 2010 - 2018
[8] BIS(NORMAL-PROPYLAMMONIUM) TETRACHLOROPLUMBATE
MERESSE, A
DAOUD, A
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 : 194 - 196
[9] Synthesis, structure, and properties of organic-inorganic perovskites and related materials
Mitzi, DB
[J]. PROGRESS IN INORGANIC CHEMISTRY, VOL 48, 1999, 48 : 1 - 121
[10] Synthesis, crystal structure, and optical and thermal properties of (C4H9NH3)(2)MI(4) (M=Ge, Sn, Pb)
Mitzi, DB
[J]. CHEMISTRY OF MATERIALS, 1996, 8 (03) : 791 - 800

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