First intramolecular enantioselective iridium-catalysed allylic aminations

被引：97

作者：

Welter, C ^{[1
]}

Koch, O ^{[1
]}

Lipowsky, G ^{[1
]}

Helmchen, G ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 07期

关键词：

D O I：

10.1039/b400023d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enantioselective iridium-catalysed intramolecular allylic aminations, using phosphinooxazolines or phosphorus amidites as ligands, provided ee values of > 90%, at a catalyst loading of < 0.5 mol-%, and displayed a marked preference for intra- over corresponding intermolecular reactions.

引用

页码：896 / 897

页数：2

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