Manganese clusters with relevance to photosystem II

被引:515
作者
Mukhopadhyay, S
Mandal, SK
Bhaduri, S
Armstrong, WH
机构
[1] Boston Coll, Eugene F Merkert Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA
[2] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA
[3] Dow Corning Corp, Midland, MI 48686 USA
关键词
D O I
10.1021/cr0206014
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Achieving a synthetic analogue of the photosystem II (PS II) active site that possesses functional activity remains one of the challenges in the field of bioinorganic chemistry. In this area, the synthesis of high-valent oxo-bridged multinuclear manganese clusters with varied nuclearity continues to be the center of activity. This review covers the synthesis and properties of biologically relevant dinuclear, trinuclear, and tetranuclear manganese complexes reported during the period 1975-2003 with emphasis on recently developed systems that have direct and/or indirect implications toward the PSII water oxidase. It also briefly discusses the spectroscopic properties of the PSII Mn//4 cluster and proposed mechanistic aspects of oxygen evolution that have been previously reviewed.
引用
收藏
页码:3981 / 4026
页数:46
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