Existence of Nearly-Free Hydrogen Bonds in an Ionic Liquid, N,N-Diethyl-N-methyl-N-(2-methoxyethyl) Ammonium Tetrafluoroborate-Water at 77 K

被引：31

作者：

Yoshimura, Y. ^{[1
]}

Goto, T. ^{[1
]}

Abe, H. ^{[2
]}

Imai, Y. ^{[2
]}

机构：

[1] Natl Def Acad, Dept Appl Chem, Yokosuka, Kanagawa 2398686, Japan

[2] Natl Def Acad, Dept Mat Sci & Engn, Yokosuka, Kanagawa 2398686, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2009年 / 113卷 / 23期

关键词：

SOLVATION DYNAMICS; 1-HEXYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE; VIBRATIONAL SPECTROSCOPY; SUPERCOOLED WATER; MIXTURES; COUMARIN-153; RELAXATION; TRANSITION; SOLVENTS; CHLORIDE;

D O I：

10.1021/jp902125f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

When making the glassy water-ionic liquid, N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium tetrafluoroborate [DEME][BF4] solution, the water molecule existing as a single molecule without self-associated state is preserved even at 77 K and survives not to form the hydrogen bond network among themselves as in pure H2O liquid. The water molecule might loosely interact with BF4- anions: At water-rich concentration, H2O ice crystals and the water molecules in the ionic liquid coexist as a mixture, which may result from microheterogeneities in the solid aqueous ionic liquid solution.

引用

页码：8091 / 8095

页数：5

共 39 条

[1]

Adhikari A, 2007, J PHYS CHEM B, V111, P12809, DOI [10.1021/jp075693l, 10.1021/jp0756931]

[2]

SUPERCOOLED WATER - APPROACHING THE LIMITS [J].

ANGELL, CA .

NATURE, 1988, 331 (6153) :206-207

[3]

GLASS-FORMING COMPOSITION REGIONS AND GLASS TRANSITION TEMPERATURES FOR AQUEOUS ELECTROLYTE SOLUTIONS [J].

ANGELL, CA ;

SARE, EI .

JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (03) :1058-&

[4]

How does water affect the dynamics of the room-temperature ionic liquid 1-hexyl-3-methylimidazolium hexafluorophosphate and the fluorescence spectroscopy of coumarin-153 when dissolved in it? [J].

Annapureddy, Harsha V. R. ;

Hu, Zhonghan ;

Xia, Junchao ;

Margulis, Claudio J. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (06) :1770-1776

[5]

Solvation dynamics and proton transfer in supramolecular assemblies [J].

Bhattacharyya, K .

ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (02) :95-101

[6]

Cammarata L, 2001, PHYS CHEM CHEM PHYS, V3, P5192, DOI 10.1039/b106900d

[7]

Effect of water, methanol, and acetonitrile on solvent relaxation and rotational relaxation of coumarin 153 in neat 1-hexyl-3-methylimidazolium hexafluorophosphate [J].

Chakrabarty, D ;

Chakraborty, A ;

Seth, D ;

Sarkar, N .

JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (09) :1764-1769

[8]

ATR-FTIR spectroscopic studies on aqueous LiClO4, NaClO4, and Mg(ClO4)2 solutions [J].

Chen, Y ;

Zhang, YH ;

Zhao, LJ .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (03) :537-542

[9]

FREQUENCY SHIFT-ENTHALPY CORRELATION FOR A GIVEN DONOR WITH VARIOUS HYDROGEN-BONDING ACIDS [J].

DRAGO, RS ;

OBRYAN, N ;

VOGEL, GC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (13) :3924-&

[10]

Ionic liquids. Green solvents for the future [J].

Earle, MJ ;

Seddon, KR .

PURE AND APPLIED CHEMISTRY, 2000, 72 (07) :1391-1398

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