Polyaniline nanotubules obtained in room-temperature ionic liquids

被引:54
作者
Wei, Di
Kvarnstrom, Carita
Lindfors, Tom
Ivaska, Ari
机构
[1] Abo Akad Univ, Proc Chem Ctr, Analyt Chem Lab, SF-20500 Turku, Finland
[2] Abo Akad Univ, GSMR, SF-20500 Turku, Finland
基金
芬兰科学院;
关键词
polyaniline; electropolymerization; ionic liquids; organic photovoltaics and light emitting diodes;
D O I
10.1016/j.elecom.2006.07.024
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Polyaniline (PANI) nanotubules were synthesized electrochemically on a modified ITO glass in the room-temperature ionic liquid (IL), 1-butyl-3-methyl-imidazolium hexafluorophosphate (BMIPF(6)) containing 1 M trifluoroacetic acid. Tubular structures of PANI with the diameter of similar to 120 nm were shown by scanning electron microscopy. The resulting PANI from this IL media is further characterized by Raman and Fourier transform infrared spectra, which show that the PANI nanotubules are in the conducting form. This provides a possible IL media to functionalize conducting PANI with, for example, single wall carbon nanotubes for the application of organic photovoltaics and light emitting diodes.
引用
收藏
页码:1563 / 1566
页数:4
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