A rational self-sacrificing template route to β-Bi2O3 nanotube arrays

被引:92
作者
Yang, BJ
Mo, MS
Hu, HM
Li, C
Yang, XG
Li, QW
Qian, YT [1 ]
机构
[1] Univ Sci & Technol China, Struct Res Lab, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[3] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Anhui, Peoples R China
关键词
bismuth oxide; nanostructures; nanotubes; synthesis design;
D O I
10.1002/ejic.200300966
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Arrayed beta-Bi2O3 nanotubes (NTs) were synthesized for the first time through a rational "self-sacrificing template" route, simply by oxidizing the precursor metallic bismuth NT arrays in air at 200-220 degreesC for 14-18 h. XRD, TEM, and HRTEM characterizations show that the prepared beta-Bi2O3 samples are all phase pure and the beta-Bi2O3 NTs have uniform diameters of approximately 3-6 nm and lengths up to several micrometers. The optical absorption and photoluminescence (PL) characteristics of the prepared samples were investigated. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
引用
收藏
页码:1785 / 1787
页数:3
相关论文
共 30 条
[1]   Smoke sensor on the base of Bi2O3 sesquioxide [J].
Adamian, ZN ;
Abovian, HV ;
Aroutiounian, VM .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 35 (1-3) :241-243
[2]   THE STRUCTURE OF BETA-BI2O3 FROM POWDER NEUTRON-DIFFRACTION DATA [J].
BLOWER, SK ;
GREAVES, C .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :587-589
[3]  
Caruso RA, 2001, ADV MATER, V13, P1577, DOI 10.1002/1521-4095(200110)13:20<1577::AID-ADMA1577>3.0.CO
[4]  
2-S
[5]   The stabilization of beta-Bi2O3 by CeO2 [J].
Chen, XL ;
Eysel, W .
JOURNAL OF SOLID STATE CHEMISTRY, 1996, 127 (01) :128-130
[6]   Fabrication and characterization of nanotubular semiconductor oxides In2O3 and Ga2O3 [J].
Cheng, B ;
Samulski, ET .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (12) :2901-2902
[7]   Optical properties of surface-modified Bi2O3 nanoparticles [J].
Dong, WT ;
Zhu, CS .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2003, 64 (02) :265-271
[8]   Functionalized boron nitride nanotubes with a stannic oxide coating: A novel chemical route to full coverage [J].
Han, WQ ;
Zettl, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (08) :2062-2063
[9]   A general template-based method for the preparation of nanomaterials [J].
Hulteen, JC ;
Martin, CR .
JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (07) :1075-1087
[10]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58