Structure and spectroscopic properties of a luminescent inorganic cyclophane from self-assembly of copper(I) and two ligand components

被引：51

作者：

Chan, CK ^{[1
]}

Cheung, KK ^{[1
]}

Che, CM ^{[1
]}

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 02期

关键词：

D O I：

10.1039/cc9960000227

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of trithiocyanuric acid (H(3)L) with CuCl(PPh(3))(3) gives [(CuPPh(3))(6)L(2)], the structure of which shows two parallel triazine rings held in a close proximity of 3.07 Angstrom by six Cu-S bridges; the complex [(CuPPh(3))(6)L(2)] shows visible emission in the solid state and in fluid solution at room temperature.

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页码：227 / 228

页数：2

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