Structural relaxation of dense suspensions of soft giant micelles

被引:35
作者
Sigel, R
Pispas, S
Vlassopoulos, D
Hadjichristidis, N
Fytas, G
机构
[1] Inst Elect Struct & Laser, FORTH, GR-71110 Iraklion, Greece
[2] Univ Athens, Dept Chem, GR-15771 Athens, Greece
[3] Max Planck Inst Polymer Res, D-55021 Mainz, Germany
关键词
D O I
10.1103/PhysRevLett.83.4666
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The dynamics of liquid-like ordered giant colloidal micelles in the wave vector range around the peak of the structure factor is explored using photon correlation spectroscopy. No thermodynamic slowing down of the collective density fluctuations is found, whereas the long-time diffusion coefficient follows the concentration dependence of the suspension viscosity. Polymer-layer mediated effects are proposed to govern the physics of this unexpected behavior.
引用
收藏
页码:4666 / 4669
页数:4
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共 23 条
  • [1] Rheology and dynamics of colloidal suspensions
    Banchio, AJ
    Bergenholtz, J
    Nägele, G
    [J]. PHYSICAL REVIEW LETTERS, 1999, 82 (08) : 1792 - 1795
  • [2] The glass transition dynamics of polymer micronetwork colloids. A mode coupling analysis
    Bartsch, E
    Frenz, V
    Baschnagel, J
    Schartl, W
    Sillescu, H
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (09) : 3743 - 3756
  • [3] Nonexponential relaxation of density fluctuations in charge-stabilized colloids
    Baur, P
    Nagele, G
    Klein, R
    [J]. PHYSICAL REVIEW E, 1996, 53 (06): : 6224 - 6237
  • [5] Thermodynamic effects on internal relaxation in diblock copolymers
    Boudenne, N
    Anastasiadis, SH
    Fytas, G
    Xenidou, M
    Hadjichristidis, N
    Semenov, AN
    Fleischer, G
    [J]. PHYSICAL REVIEW LETTERS, 1996, 77 (03) : 506 - 509
  • [6] Microscopic theory of polymer-mediated interactions between spherical particles
    Chatterjee, AP
    Schweizer, KS
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (23) : 10464 - 10476
  • [7] STAR SHAPED POLYMERS - A MODEL FOR THE CONFORMATION AND ITS CONCENTRATION-DEPENDENCE
    DAOUD, M
    COTTON, JP
    [J]. JOURNAL DE PHYSIQUE, 1982, 43 (03): : 531 - 538
  • [8] COLLECTIVE DYNAMICS OF TETHERED CHAINS - BREATHING MODES
    FARAGO, B
    MONKENBUSCH, M
    RICHTER, D
    HUANG, JS
    FETTERS, LJ
    GAST, AP
    [J]. PHYSICAL REVIEW LETTERS, 1993, 71 (07) : 1015 - 1018
  • [9] Density profile of spherical polymer brushes
    Forster, S
    Wenz, E
    Lindner, P
    [J]. PHYSICAL REVIEW LETTERS, 1996, 77 (01) : 95 - 98
  • [10] Probing collective motions of terminally anchored polymers
    Fytas, G
    Anastasiadis, SH
    Seghrouchni, R
    Vlassopoulos, D
    Li, JB
    Factor, BJ
    Theobald, W
    Toprakcioglu, C
    [J]. SCIENCE, 1996, 274 (5295) : 2041 - 2044