Synthesis, characterisation and aqueous behaviour of a one-ended perfluorocarbon-modified poly(ethylene glycol)

被引：19

作者：

Boschet, F

Branger, C

Margaillan, A

Condamine, E

机构：

[1] Univ Toulon & Var, Equipe Accueil Mat Final Specif, Lab Chim Appl, F-83957 La Garde, France

[2] Univ Rouen, Inst Rech Chim Organ Fine, UMR CNRS 6014, Equipe Chim Organ & Biol Struct, F-76131 Mont St Aignan, France

来源：

POLYMER | 2002年 / 43卷 / 19期

关键词：

hydrophobically associating PEG; rheological properties; fluorine NMR;

D O I：

10.1016/S0032-3861(02)00397-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Establishing structure-properties relationships for an associative polymer requires a precise knowledge of its structure. In previous works, we studied water-soluble telechelic perfluorocarbon (C8F17) derivatives of poly(ethylene glycol)s. They exhibit stronger hydrophobic intermolecular associations than the corresponding hydrocarbon derivatives (C8H17). We now report the synthesis and study of one-ended perfluorocarbon derivative of poly(ethylene glycol). The composition and structure of this polymer were elucidated before analysing its behaviour in aqueous solution by viscosimetry and F-19 NMR. The synthesis procedure allows us to reach total grafting. This polymer presents a micellar behaviour above 2 X 10(-4) g/ml and an associative behaviour above 10(-3) g/ml. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：5329 / 5334

页数：6

共 35 条

[1] A COMPUTER-SIMULATION FOR THE AGGREGATION OF ASSOCIATING POLYMERS [J].