C-H•••O hydrogen bonding induced guest inclusion and supramolecular isomerism in 1,3,5-tris(4-cyanobenzoyl)benzene

被引：29

作者：

Kumar, VSS ^{[1
]}

Pigge, FC ^{[1
]}

Rath, NP ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem & Biochem, St Louis, MO 63121 USA

来源：

CRYSTAL GROWTH & DESIGN | 2004年 / 4卷 / 04期

关键词：

D O I：

10.1021/cg034252y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystallization of 1,3,5-tris(4-cyanobenzoyl)benzene (1) from EtOAc, MeNO2, and 3-pentanone results in formation of isostructural inclusion complexes mediated by weak hydrogen bonding interactions involving aryl C-H donors and heteroatom acceptors from nitrile, carbonyl, and nitro groups. The solvent guests occupy interlayer channels within a porous triaroylbenzene host network.

引用

页码：651 / 653

页数：3

共 32 条

[1] Do polymorphic compounds make good cocrystallizing agents?: A structural case study that demonstrates the importance of synthon flexibility [J].

Aakeröy, CB ;

Beatty, AM ;

Helfrich, BA ;

Nieuwenhuyzen, M .

CRYSTAL GROWTH & DESIGN, 2003, 3 (02) :159-165

[2]

Aoyama Y, 1998, TOP CURR CHEM, V198, P131

[3]

Atwood J., 1991, INCLUSION COMPOUNDS, V4

[4]

Atwood J. L., 1996, Comprehensive Supramolecular Chemistry, V6

[5]

Bishop R, 1999, SYNLETT, P1351

[6]

Bourne SA, 2001, CHEM COMMUN, P861

[7]

Desiraju G. R., 1999, WEAK HYDROGEN BOND S

[8]

Desiraju G. R., 1989, DESIGN ORGANIC SOLID

[9] Crystal gazing: Structure prediction and polymorphism [J].

Desiraju, GR .

SCIENCE, 1997, 278 (5337) :404-405

[10] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

← 1 2 3 4 →