A Neutral Ga6 Octahedron: Synthesis, Structure, and Aromaticity

被引：52

作者：

Quillian, Brandon

Wei, Pingrong

Wannere, Chaitanya S.

Schleyer, Paul v. R. ^{[1
]}

Robinson, Gregory H.

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 09期

基金：

美国国家科学基金会;

关键词：

COMPOUND; AL;

D O I：

10.1021/ja809945v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Potassium graphite reduction of L:Ga(Mes)Cl-2 [L: = :C{(i-Pr)NC(Me)}(2), Mes = 2,4,6-Me3C6H2] (1) in hexane yields the organogallium dimer L:(Mes)(Cl)Ga-Ga(Cl)(Mes):L (2), while potassium reduction of 1 in toluene affords the neutral aromatic Ga-6 octahedron L:Ga[Ga(4)Mes(4)]Ga:L (3).

引用

收藏

页码：3168 / +

页数：3

相关论文

共 22 条

[1]

Baker RJ, 2003, EUR J INORG CHEM, P2446

[2] Nucleus-independent chemical shifts (NICS) as an aromaticity criterion [J].

Chen, ZF ;

Wannere, CS ;

Corminboeuf, C ;

Puchta, R ;

Schleyer, PV .

CHEMICAL REVIEWS, 2005, 105 (10) :3842-3888

[3]

Donchev A, 2002, Z ANORG ALLG CHEM, V628, P157, DOI 10.1002/1521-3749(200201)628:1<157::AID-ZAAC157>3.0.CO

[4]

2-4

[5] CsTl: A new example of tetragonally compressed Tl-6(6-) octahedra. Electronic effects and packing requirements in the diverse structures of ATl (A=Li, Na, K, Cs) [J].

Dong, ZC ;

Corbett, JD .

INORGANIC CHEMISTRY, 1996, 35 (08) :2301-2306

[6] Synthesis, structure, and oxidation of donor-stabilized Gallium(I) iodide: Ga8I8 center dot 6PEt(3) [J].

Doriat, CU ;

Friesen, M ;

Ecker, EBA ;

Schnockel, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (18) :1969-1971

[7]

Driess M., 2004, Molecular Clusters of the Main Group Elements

[8]

Glendening E. D., 2001, Nbo 5.0

[9]

HILLER W, 1991, ANGEW CHEM INT EDIT, V30, P179

[10] Antiaromaticity in bare deltahedral silicon clusters satisfying Wade's and Hirsch's rules: An apparent correlation of antiaromaticity with high symmetry [J].

King, RB ;

Heine, T ;

Corminboeuf, C ;

Schleyer, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (02) :430-431