Bacterial-Cellulose-Derived Carbon Nanofiber@MnO2 and Nitrogen-Doped Carbon Nanofiber Electrode Materials: An Asymmetric Supercapacitor with High Energy and Power Density

被引:578
作者
Chen, Li-Feng [1 ]
Huang, Zhi-Hong [1 ]
Liang, Hai-Wei [1 ]
Guan, Qing-Fang [1 ]
Yu, Shu-Hong [1 ]
机构
[1] Univ Sci & Technol China, CAS Key Lab Mech Behav & Design Mat, Hefei Natl Lab Phys Sci Microscale, Div Nanomat & Chem,Dept Chem, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
bacterial cellulose; carbon nanofibers; asymmetric supercapacitors; manganese dioxide; nitrogen doping; MANGANESE-DIOXIDE; NANOSCALE MNO2; PERFORMANCE; GRAPHENE; OXIDE; CAPACITORS; DEPOSITION;
D O I
10.1002/adma.201204949
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new kind of high-performance asymmetric supercapacitor is designed with pyrolyzed bacterial cellulose (p-BC)-coated MnO2 as a positive electrode material and nitrogen-doped p-BC as a negative electrode material via an easy, efficient, large-scale, and green fabrication approach. The optimal asymmetric device possesses an excellent supercapacitive behavior with quite high energy and power density. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4746 / 4752
页数:7
相关论文
共 35 条
[1]   Flexible Zn2SnO4/MnO2 Core/Shell Nanocable-Carbon Microfiber Hybrid Composites for High-Performance Supercapacitor Electrodes [J].
Bao, Lihong ;
Zang, Jianfeng ;
Li, Xiaodong .
NANO LETTERS, 2011, 11 (03) :1215-1220
[2]   Long-term cycling behavior of asymmetric activated carbon/MnO2 aqueous electrochemical supercapacitor [J].
Brousse, Thierry ;
Taberna, Pierre-Louis ;
Crosnier, Olivier ;
Dugas, Romain ;
Guillemet, Philippe ;
Scudeller, Yves ;
Zhou, Yingke ;
Favier, Frederic ;
Belanger, Daniel ;
Simon, Patrice .
JOURNAL OF POWER SOURCES, 2007, 173 (01) :633-641
[3]   Synthesis of Nitrogen-Doped Porous Carbon Nanofibers as an Efficient Electrode Material for Supercapacitors [J].
Chen, Li-Feng ;
Zhang, Xu-Dong ;
Liang, Hai-Wei ;
Kong, Mingguang ;
Guan, Qing-Fang ;
Chen, Ping ;
Wu, Zhen-Yu ;
Yu, Shu-Hong .
ACS NANO, 2012, 6 (08) :7092-7102
[4]   Recent Advances in Manganese Oxide Nanocrystals: Fabrication, Characterization, and Microstructure [J].
Chen, Zhiwen ;
Jiao, Zheng ;
Pan, Dengyu ;
Li, Zhen ;
Wu, Minghong ;
Shek, Chan-Hung ;
Wu, C. M. Lawrence ;
Lai, Joseph K. L. .
CHEMICAL REVIEWS, 2012, 112 (07) :3833-3855
[5]  
China Patent, Chinese Patent, Patent No. [ZL96100534.3, 96100534]
[6]   3D Macroporous Graphene Frameworks for Supercapacitors with High Energy and Power Densities [J].
Choi, Bong Gill ;
Yang, MinHo ;
Hong, Won Hi ;
Choi, Jang Wook ;
Huh, Yun Suk .
ACS NANO, 2012, 6 (05) :4020-4028
[7]   Asymmetric Supercapacitors Based on Graphene/MnO2 and Activated Carbon Nanofiber Electrodes with High Power and Energy Density [J].
Fan, Zhuangjun ;
Yan, Jun ;
Wei, Tong ;
Zhi, Linjie ;
Ning, Guoqing ;
Li, Tianyou ;
Wei, Fei .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (12) :2366-2375
[8]   Electroless deposition of nanoscale MnO2 on ultraporous carbon nanoarchitectures:: Correlation of evolving pore-solid structure and electrochemical performance [J].
Fischer, Anne E. ;
Saunders, Matthew P. ;
Pettigrew, Katherine A. ;
Rolison, Debra R. ;
Long, Jeffrey W. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (03) :A246-A252
[9]   Incorporation of homogeneous, nanoscale MnO2 within ultraporous carbon structures via self-limiting electroless deposition:: Implications for electrochemical capacitors [J].
Fischer, Anne E. ;
Pettigrew, Katherine A. ;
Rolison, Debra R. ;
Stroud, Rhonda M. ;
Long, Jeffrey W. .
NANO LETTERS, 2007, 7 (02) :281-286
[10]   Highly Stable Performance of Supercapacitors from Phosphorus-Enriched Carbons [J].
Hulicova-Jurcakova, Denisa ;
Puziy, Alexander M. ;
Poddubnaya, Olga I. ;
Suarez-Garcia, Fabian ;
Tascon, Juan M. D. ;
Lu, Gao Qing .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (14) :5026-+