Butyltellurolate ligands in cluster synthesis: Molecular structures of Ag6Te6, Ag32Te25 and Ag48Te36 complexes

被引：33

作者：

Corrigan, JF ^{[1
]}

Fenske, D ^{[1
]}

机构：

[1] UNIV KARLSRUHE,INST ANORGAN CHEM,D-76128 KARLSRUHE,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000943

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bu(n)TeSiMe(3) reacts with silver(I) chloride in the presence of PEt(3) to yield the following series of cluster complexes depending on the relative amount of phosphine used: [Ag-6(mu 3-TeBu(n))(4)(mu-TeBu(n))(2)(PEt(3))(4)] 1, [Ag-32(mu(3)-TeBu(n))(18)-Te-7(PEt(3))(6)] 2 and [Ag-48(mu(3)-TeBu(n))(24)Te-12(PEt(3))(14)] 3; the molecular structures of 2 and 3 are described.

引用

页码：943 / 944

页数：2

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