Convenient Synthesis of Tetra- and Hexaarylanthracenes by Means of RuH2(CO)(PPh3)3-Catalyzed C-H Arylation of Anthraquinone with Arylboronates

被引：56

作者：

Kitazawa, Kentaroh ^{[1
]}

Kochi, Takuya ^{[1
]}

Sato, Mitsuo ^{[1
]}

Kakiuchi, Fumitoshi ^{[1
]}

机构：

[1] Keio Univ, Dept Chem, Fac Sci & Technol, Kohoku Ku, Kanagawa 2238522, Japan

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 09期

关键词：

POLYCYCLIC AROMATIC-HYDROCARBONS; ORGANIC SEMICONDUCTORS; PHENYLATED ANTHRACENES; BOND-CLEAVAGE; FLUORESCENCE; DERIVATIVES; KETONES; ALKYNES; ACENES; ZIRCONACYCLOPENTADIENES;

D O I：

10.1021/ol900393x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new method for the synthesis of multiarylanthracenes was developed by means of the RuH2(CO)(PPh3)(3)-Catalyzed arylation of anthraquinone with arylboronates. This method consists of short and straightforward sequences starting with an easily accessible anthraquinone and is applicable to the syntheses of various multiarylanthracenes including those bearing twisted backbones.

引用

页码：1951 / 1954

页数：4

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