Hydrosilylation of olefins with monosilane in the presence of lithium aluminum hydride

被引：21

作者：

Kobayashi, M ^{[1
]}

Itoh, M ^{[1
]}

机构：

[1] MITSUI TOATSU CHEM CO LTD, CENT RES LAB, SAKAE KU, YOKOHAMA, KANAGAWA 247, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 12期

关键词：

D O I：

10.1246/cl.1996.1013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrosilylation reactions of 1-hexene and ethylene with SiH4 occurs in the presence of LiAlH4 as a catalyst. Hexylsilane and dihexylsilane were produced from 1-hexene and SiH4. Ethylsilane was produced from ethylene and SiH4. The reaction mechanism involving SiH4 and the alkyl anion, which is formed by the interaction between LiAlH4 and the olefin, has been proposed.

引用

页码：1013 / 1014

页数：2

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