[Mn(bpm)(N3)2]n:: A one-dimensional coordination polymer exhibiting strong ferromagnetic-antiferromagnetic alternating interactions

被引:52
作者
Tang, LF [1 ]
Zhang, L [1 ]
Li, LC [1 ]
Cheng, P [1 ]
Wang, ZH [1 ]
Wang, JT [1 ]
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词
D O I
10.1021/ic990878v
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Ferromagnetic and antiferromagnetic alternating interactions within and between chains, respectively, were interpreted for a one-dimensional coordination polymer having high-spin (S = 5/2) Mn-II centers bridged by azido ligands, namely, [Mn(bpm)(N-3)(2)](n) (bpm = bis-(pyrazol-1-yl) methane).
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页码:6326 / +
页数:4
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