Crosslinking in phenylethynyl-terminated polyimides

被引:24
作者
Hinkley, JA [1 ]
Jensen, BJ [1 ]
机构
[1] NASA,LANGLEY RES CTR,COMPOSITES & POLYMERS BRANCH,HAMPTON,VA 23681
关键词
D O I
10.1088/0954-0083/8/4/008
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Stress relaxation of cured phenylethynyl-terminated polyimides was used to estimate their equilibrium rubbery moduli. The corresponding concentrations of elastically effective chains derived from classical rubber elasticity theory were less than one-fifth what would be expected if every chain end participated in a crosslink. A model is proposed to allow the calculation of the average crosslink functionalities.
引用
收藏
页码:599 / 605
页数:7
相关论文
共 13 条
[1]  
FERRY JD, 1980, VISCOELASTIC PROPERT, P415
[2]  
FERRY JD, 1980, VISCOELASTIC PROPERT, P408
[3]   ENTANGLEMENT INTERACTIONS IN POLYMERS AND THE CHAIN CONTOUR CONCENTRATION [J].
GRAESSLEY, WW ;
EDWARDS, SF .
POLYMER, 1981, 22 (10) :1329-1334
[4]   LONG-TIME RELAXATION OF POLYMER NETWORKS [J].
HEINRICH, G ;
VILGIS, TA .
MACROMOLECULES, 1992, 25 (01) :404-407
[5]   CHEMISTRY AND PROPERTIES OF IMIDE OLIGOMERS END-CAPPED WITH PHENYLETHYNYLPHTHALIC ANHYDRIDES [J].
HERGENROTHER, PM ;
SMITH, JG .
POLYMER, 1994, 35 (22) :4857-4864
[6]  
HERGENROTHER PM, 1979, 177 AM CHEM SOC PETR, V24, P243
[7]  
HINKLEY JA, 1989, HIGH PERFORM POLYM, V1, P41
[8]  
JENSEN BJ, 1994, POLYM PREPR, V35, P539
[9]   RELATION OF ELASTIC-MODULUS TO CROSSLINK AND ENTANGLEMENT CONCENTRATIONS IN RUBBER NETWORKS [J].
LANGLEY, NR ;
POLMANTEER, KE .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1974, 12 (06) :1023-1034
[10]  
LEE CYC, 1983, 28TH NATL SAMPE S EX, P699