Preparation and x-ray crystallographic characterisation of the trititanate [Ti3O(mu-OPr(i))(3)(OPr(i))(4){Me2C(O)CH=C(O)CH2C(O)Me-2}], a reaction product of [Ti(OPri)(4)] and propan-2-one

被引：18

作者：

Barkley, JV ^{[1
]}

Cannadine, JC ^{[1
]}

Hannaford, I ^{[1
]}

Harding, MM ^{[1
]}

Steiner, A ^{[1
]}

Tallon, J ^{[1
]}

Whyman, R ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 7ZD,MERSEYSIDE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 17期

关键词：

D O I：

10.1039/a704000h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Ti(OPri)(4) with propan-2-one, under initially anhydrous conditions, yields a colourless moisture-sensitive crystalline product which is structurally identified as the trinuclear oxoalkoxide [Ti3O(mu-OPri)(3)(OPri)(4){Me2C(O)CH- = C(O)CH2C(O)Me-2}] containing a coordinated C-9 ligand derived from the condensation of propan-2-one.

引用

页码：1653 / 1654

页数：2