A thermoanalytical study of copper(I) thiocarbamide compounds

被引：31

作者：

Krunks, M

Leskelä, T

Mutikainen, I

Niinistö, L

机构：

[1] Aalto Univ, Inorgan & Analyt Chem Lab, FIN-02015 Espoo, Finland

[2] Tallinn Univ Technol, Inst Mat Technol, EE-19086 Tallinn, Estonia

[3] Univ Helsinki, Inorgan Chem Lab, FIN-00014 Helsinki, Finland

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 1999年 / 56卷 / 02期

关键词：

copper thiocarbamide complex; DTA; spray pyrolysis; TG;

D O I：

10.1023/A:1010184107901

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Hydrated isostructural 1:3 complexes of copper(I) chloride and bromide with thiourea were synthesised and their thermal decomposition studied by simultaneous TG/DTA complemented by ex situ FTIR and XRD studies. The decomposition of Cu(tu)(3)Cl . H2O is initiated by dehydration around 100 degrees C, followed by a total multi-step degradation of the structure in the temperature range of 200-600 degrees C. The counter ion has some influence on the temperatures and composition of the solid residue. The results were compared with those obtained with the 1:1 complex Cu(tu)Cl . 1/2H(2)O.

引用

页码：479 / 484

页数：6

共 7 条

[1] SIMILARITIES IN THE CHEMICAL MECHANISMS OF CUINSE2 AND CDS THIN-FILM FORMATION BY CHEMICAL SPRAY PYROLYSIS [J].